CsCl crystallizes in a unit cell that contains the Cs^ ion at ... | Filo
CsCl crystallizes in a unit cell that contains the Cs^ ion at ... | Filo
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SOLVED: Consider the CsCl crystal, which has one Cs-Cl pair per unit cell and a lattice parameter a of 0.412 nm. The electronic polarizability of Cs is 3.35 × 10^-4 F m^2, and that of Cl is 3.40 × 10^-4 F m^2. The mean ionic polarizability per ion pair (per Cs-Cl ion) is 6.0 × 10^-4 F m^2. Remember that there is only one ion pair per unit cell in CsCl (see Fig 1.38, p. 54). Calculate the relative permittivity under DC operation and at optical frequencies (HINT: see section 7.3.4).
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